French in Action - Series of instructional French videos following an American student in Paris. Produced by Yale in 1987.
Radio Lingua Network: French - French podcasts at the beginner to intermediate level. "Coffee Break French" is particularly popular.
Foreign Service Institute: French Basic Course - Audio course designed by the US Foreign Service Institute to help diplomats attain conversational proficiency.
Ma France - BBC-sponsored video course for intermediate students.
Open Culture: Learn French for Free - Collection of audio-visual French lessons
Radio France Internationale: Learn French - Check out "The News in Simple French" for their simplified broadcast (with transcript!).
TED Talks in French - These videos are frequently accompanied by transcripts in French and English.
-- From Butler University Libraries: